Acetone → 1,2-Decanediol

HRID 1076940

反応式

HRID 1076940 の反応式
CC(C)=[O:3].[CH2:5]1[O:15][CH:6]1[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].S(=O)(=O)(O)O>>[CH2:5]([OH:15])[CH:6]([OH:3])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]

参加物

4

反応物 3

HCID 180AcetoneHCID 1118Sulfuric AcidHCID 169931,2-Epoxydecane

生成物 1

HCID 791411,2-Decanediol

実験手順

A homogeneous clear solution is prepared by adding 3 moles of acetone to 1 mole of 1-decene oxide at room temperature. After adding 50 grams of 5% aqueous sulfuric acid to the solution, the acetone is evaporated off and the resulting solution is neutralized by adding an aqueous sodium hydroxide. The neutralized solution is extracted with pet ether and the extract dried over anhydrous magnesium sulfate. The pet ether is stripped off and 1,2-decanediol is obtained by distilling under vacuo.

後処理

  1. customA homogeneous clear solution is prepared
  2. customthe acetone is evaporated off
  3. additionby adding an aqueous sodium hydroxide
  4. extractionThe neutralized solution is extracted with pet ether
  5. dry with materialthe extract dried over anhydrous magnesium sulfate

出典と根拠

ORDレコード
ord-00b68330929d4bfa9e7c1d94eb424ed9
出典データセット
uspto-grants-1976_05
特許番号
US03959185

関連ノート

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