Acetone → 1,2-Decanediol

HRID 1076941

反応式

HRID 1076941 の反応式
CC(C)=[O:3].C1OC1CCCCCCC.[CH2:15]1[O:25][CH:16]1[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]>>[CH2:15]([OH:25])[CH:16]([OH:3])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]

参加物

4

反応物 3

HCID 180AcetoneHCID 169931,2-EpoxydecaneHCID 5511812-Heptyloxirane

生成物 1

HCID 791411,2-Decanediol

実験手順

A homogeneous clear solution is prepared by adding 3 moles of acetone to 1 mole of a mixture of 1-nonene oxide and 1-decene oxide at room temperature. After 50 grams of 5% aqueous sulfuric acid to the solution, the acetone is evaporated off and the resulting solution is neutralized by adding an aqueous sodium hydroxide. The neutralized solution is extracted with pet ether and the extract dried over anhydrous magnesium sulfate. The pet ether is stripped off and a mixture of 1,2-nonanediol and 1,2-decanediol is obtained by distilling under vacuo.

後処理

  1. customA homogeneous clear solution is prepared
  2. customAfter 50 grams of 5% aqueous sulfuric acid to the solution, the acetone is evaporated off
  3. additionby adding an aqueous sodium hydroxide
  4. extractionThe neutralized solution is extracted with pet ether
  5. dry with materialthe extract dried over anhydrous magnesium sulfate
  6. additiona mixture of 1,2-nonanediol

出典と根拠

ORDレコード
ord-695aadb6f1de4cf78c0370d7d2733131
出典データセット
uspto-grants-1976_05
特許番号
US03959185

関連ノート

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