Ethylene → Ethene propene 1-butene

HRID 1077114ノート

反応式

HRID 1077114 の反応式
[Al+3].[Cl-].[Cl-].[Cl-].[Cl-].[CH2:6]([Al+]CC)[CH3:7].[CH2:11]=[CH:12][CH3:13].[H][H].[CH3:16]/[CH:17]=[CH:18]/[CH3:19].CCC=C.C=C>>[CH2:11]=[CH:12][CH3:13].[CH2:6]=[CH2:7].[CH3:19][CH2:18][CH:17]=[CH2:16]

参加物

8

反応物 7

HCID 6325EthyleneHCID 78441-ButeneHCID 8252PropyleneHCID 62695trans-2-BUTENEHCID 6451240Aluminum(III) ChlorideHCID 16686102Diethyl aluminum chlorideHCID 178418361HCID 178418361、化合物

生成物 1

HCID 168434Ethene propene 1-butene

実験手順

With the aid of a catalyst of 0.014 part by weight of the TiCl3 . 0.33 AlCl3 described in Example 1 and 0.022 part by weight of diethylaluminum chloride, 20 parts by weight of propene (99%) is polymerized under a pressure of 14-9 atm. gauge and a temperature of 70° C. after adding 0.00015 part by weight of hydrogen in 60 parts by weight of a butene-2-rich C4 -cut containing 0.4% of butene-1. After a polymerization period of 6 hours, 1.0 part by weight of ethene is introduced under pressure, and the polymerization is containued for another 4 hours. After passing the reaction mixture through nozzles in the presence of 0.1 part by weight of steam, a propene-ethene-butene-1 terpolymer is obtaining having the properties as shown in the Table.

後処理

  1. customis polymerized under a pressure of 14-9 atm. gauge
  2. additionis introduced under pressure

出典と根拠

ORDレコード
ord-9aeb60ee197a472cb9c23c19d7d68caa
出典データセット
uspto-grants-1976_05
特許番号
US03959409

反応ノート

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