2,3,6-Trichlorophenol → 2,3,5-Trichloro-4-thiocyanatophenol

HRID 1077298

反応式

HRID 1077298 の反応式
ClC1C(Cl)=CC(Cl)=CC=1O.ClC1C(Cl)=CC=C(Cl)C=1O.[Cl:21][C:22]1[C:27]([Cl:28])=[C:26]([S:29][C:30]#[N:31])[C:25]([Cl:32])=[CH:24][C:23]=1[OH:33].ClC1C(Cl)=C(SC#N)C=C(Cl)C=1O>>[Cl:21][C:22]1[C:27]([Cl:28])=[C:26]([S:29][C:30]#[N:31])[C:25]([Cl:32])=[CH:24][C:23]=1[OH:33].[Cl:21][C:22]1[C:27]([Cl:28])=[C:26]([S:29][CH3:30])[C:25]([Cl:32])=[CH:24][C:23]=1[OH:33]

参加物

6

反応物 4

HCID 136182,3,6-TrichlorophenolHCID 136192,3,5-TrichlorophenolHCID 215363112,3,5-Trichloro-4-thiocyanatophenolHCID 215363122,3,6-Trichloro-4-thiocyanatophenol

生成物 2

HCID 215363112,3,5-Trichloro-4-thiocyanatophenolHCID 215363602,3,5-Trichloro-4-(methylthio)phenol

実験手順

The compound 2,3,5-trichloro-4-thiocyanatophenol is prepared in a manner similar to that of Example II using 2,3,5-trichlorophenol in lieu of 2,3,6-trichlorophenol. The compound 2,3,5-trichloro-4-(methylthio)phenol is prepared in a manner similar to that of Example II using 4.1 g. of 2,3,5-trichloro-4-thiocyanatophenol in place of 4.1 g. of 2,3,6-trichloro-4-thiocyanatophenol.

出典と根拠

ORDレコード
ord-2ae058bc4435435fbebdb1916cb366d6
出典データセット
uspto-grants-1976_05
特許番号
US03959487

関連ノート

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