化工社化工社 化学情報印刷レポート · 研究参考用
Prenderol → 5,5-Diethyl-2-(4-nitrobenzyl)-1,3,2-dioxaphosphorinan-2-oxide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Prenderol | HCID 8284 | — |
| 反応物 | (4-Nitro-benzyl)-phosphonic acid | HCID 5180708 | — |
| 生成物 | 5,5-Diethyl-2-(4-nitrobenzyl)-1,3,2-dioxaphosphorinan-2-oxide | HCID 18928100 | — |
反応手順
With 4-nitrobenzylphosphonic acid and 2,2-diethyl-1,3-propanediol, the same procedure as in Reference Example 11 was followed, to yield 5,5-diethyl-2-(4-nitrobenzyl)-1,3,2-dioxaphosphorinane-2-oxide, which was then recrystallized from ethanol-hexane to yield colorless prisms having a melting point of159° to 160° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05580863 |
| 出典データセット | uspto-grants-1996_12 |
| ORD ID | ord-928a949a82c84a0192a64854bb63df34 |
| 出典メモ | uspto-grants-1996_12 |