化工社化工社 化学情報印刷レポート · 研究参考用
(3-Cyclopentyloxy-4-methoxyphenyl)(2-furyl)methanol → (3-Cyclopentyloxy-4-methoxyphenyl)-(2-furyl)ketone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | (3-Cyclopentyloxy-4-methoxyphenyl)(2-furyl)methanol | HCID 19959391 | — |
| 触媒 | HCID 178418406 | HCID 178418406 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | (3-Cyclopentyloxy-4-methoxyphenyl)-(2-furyl)ketone | HCID 19959406 | 59.8% |
反応手順
The alcohol (3.2 g) was stirred with manganese (IV) oxide (10 g) in CH2Cl2 (100 ml) at RT for 3 h. The mixture was filtered through Celite® and the filtrate concentrated in vacuo. The residual dark oil was subjected to chromatography (SiO2) to give (3-cyclopentyloxy-4-methoxyphenyl)-(2-furyl)ketone (1.9 g); νmax (neat) 1620 cm-1.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05580888 |
| 出典データセット | uspto-grants-1996_12 |
| ORD ID | ord-a284ae3d7018462ab5de879d577cc04f |
| 出典メモ | uspto-grants-1996_12 |