Ammonia → Bismuth Citrate

HRID 1085045ノート

反応式

HRID 1085045 の反応式
[N+]([O-])([O-])=O.[O-2].[Bi+3:6].[C:7]([OH:19])(=[O:18])[CH2:8][C:9]([CH2:14][C:15]([OH:17])=[O:16])([C:11]([OH:13])=[O:12])[OH:10].N>O>[C:7]([O-:19])(=[O:18])[CH2:8][C:9]([CH2:14][C:15]([O-:17])=[O:16])([C:11]([O-:13])=[O:12])[OH:10].[Bi+3:6]

参加物

5

反応物 3

HCID 222AmmoniaHCID 311Citric AcidHCID 9947828Bismuth;oxygen(2-);nitrate

生成物 1

HCID 13135Bismuth Citrate収率 101%

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

A mixture of bismuth oxynitrate (22.96 g) and citric acid (33.60 g) in water (80 ml) was heated on a steam bath with frequent stirring for 30 min, by which time one drop of the suspension added to weak aqueous ammonia gave a clear solution. The mixture was diluted with water, filtered, and the residue washed well with water until free of nitrate and excess citric acid. The residue was dried under vacuum to give the title compound (32.18 g).

後処理

  1. temperaturewas heated on a steam bath
  2. customgave a clear solution
  3. filtrationfiltered
  4. washthe residue washed well with water until free of nitrate and excess citric acid
  5. customThe residue was dried under vacuum

出典と根拠

ORDレコード
ord-aa29c9ddf8f24aa2aa6384919d42825e
出典データセット
uspto-grants-1991_04
特許番号
US05008256

反応ノート

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