Benzene → p-acetyl-N-(alpha-methyl benzylidene) aniline

HRID 1088518ノート

反応式

HRID 1088518 の反応式
C([C:4]1[CH:9]=[CH:8][C:7]([C:10](=[O:12])[CH3:11])=[CH:6][CH:5]=1)(=O)C.[NH2:13][C:14]1C=CC=C[CH:15]=1.[CH:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1>O>[C:10]([C:7]1[CH:6]=[CH:5][C:4]([N:13]=[C:14]([CH3:15])[C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)=[CH:9][CH:8]=1)(=[O:12])[CH3:11]

参加物

5

反応物 3

HCID 241BenzeneHCID 6115AnilineHCID 138881,4-Diacetylbenzene

生成物 1

HCID 54464667p-acetyl-N-(alpha-methyl benzylidene) aniline

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A solution of p-diacetylbenzene (50 g), aniline (80 g) and benzene (120 ml) was refluxed in the presence of molecular sieve (10 g) with continuous removal of water. The crude product was crystallized from ethanol to give p-acetyl-N-(α-methyl benzylidene) aniline (XXIII). XXIII had a melting point of 205° C.

後処理

  1. customThe crude product was crystallized from ethanol

出典と根拠

ORDレコード
ord-d201f1638125472290ebfcaa4a3cefeb
出典データセット
uspto-grants-1990_10
特許番号
US04962234

反応ノート

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