Benzene → N-(1,2,3,4-tetrahydronaphthylidene) aniline

HRID 1088521ノート

反応式

HRID 1088521 の反応式
C1CC(=O)C2C(=CC=CC=2)C1.[CH2:12]([NH:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21]CC.C1C=CC=CC=1>O>[C:12]1(=[N:24][C:25]2[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=2)[C:13]2[C:18](=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH2:19][CH2:20][CH2:21]1

参加物

5

反応物 3

HCID 241BenzeneHCID 107241-TetraloneHCID 76362N-Dodecylaniline

生成物 1

HCID 11183633N-(1,2,3,4-tetrahydronaphthylidene) aniline

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A solution of α-tetralone (50 ml), dodecyl aniline (80 g) and benzene (150 ml) was refluxed in the presence of molecular sieve (100 g) with continuous removal of water. The crude product was crystallized from ethanol to give N-(1,2,3,4-tetrahydronaphthylidene) aniline (XXVI). XXVI had a melting point of 53° C.

後処理

  1. customThe crude product was crystallized from ethanol

出典と根拠

ORDレコード
ord-e154c3d869d346daa6428db55c1f5c1a
出典データセット
uspto-grants-1990_10
特許番号
US04962234

反応ノート

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