化工社化工社 化学情報印刷レポート · 研究参考用
Nitromethane → 1-Methylthio-1-methylamino-2-nitroethylene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Nitromethane | HCID 6375 | — |
| 反応物 | N-Methyl-dithiocarbonimidic acid dimethyl ester | HCID 140427 | — |
| 生成物 | 1-Methylthio-1-methylamino-2-nitroethylene | HCID 123549 | — |
反応手順
A mixture of nitromethane (3 ml), methyl carbonimidodithioic acid dimethyl ester (X, 675 mg), rare earth exchange Y-zeolite (RE 70 Na Y) (675 mg) was heated at 90°-110° C. for 72 hr. It was filtered and the solvent was removed by distillation leaving the required 1-methylamino-1-methylthio-2-nitroethene (II) as residue. m.p. 112°-114° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04967007 |
| 出典データセット | uspto-grants-1990_10 |
| ORD ID | ord-6ecac4db049f41c5b37fd8868d372dad |
| 出典メモ | uspto-grants-1990_10 |