関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Sodium Iodide | HCID 5238 | — |
| 反応物 | 3,4,5,6-Tetrabromo-o-xylene | HCID 17771 | — |
| 反応物 | Fumaronitrile | HCID 637930 | — |
| 反応物 | Sodium Bisulfite | HCID 23665763 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | 2,3-Dicyanonaphthalene | HCID 601270 | 80% |
反応手順
To 0.1 mole of tetrabromoxylene, 0.17 mole of fumaronitrile, 0.66 mole of sodium iodide and 400 ml of anhydrous dimethylformamide were added and heated with stirring at 70 to 80° C. for 7 hours. The reaction solution was added to 800 g of ice water. To the deposited precipitate, about 15 g of sodium hydrogen sulfite was added and allowed to stand overnight. After filtration by suction and drying, while 2,3-dicyanonaphthalene was obtained by recrystallization from chloroform/ethanol in yield of 80%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05081236 |
|---|
| 出典データセット | uspto-grants-1992_01 |
|---|
| ORD ID | ord-9055e085ce8c43f884016c9c975cd909 |
|---|
| 出典メモ | uspto-grants-1992_01 |
|---|
