Ammonia → HCID 178508665、化合物

HRID 1090289

反応式

HRID 1090289 の反応式
[C:1]([C:3]1[C:12]([C:13]#[N:14])=[CH:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=1)#[N:2].C[O-].[Na+].[NH3:18]>CO>[NH:14]=[C:13]1[C:12]2[CH:11]=[C:10]3[CH:9]=[CH:8][CH:7]=[CH:6][C:5]3=[CH:4][C:3]=2[C:1](=[NH:18])[NH:2]1

参加物

5

反応物 3

HCID 222Ammonia2 回HCID 6012702,3-DicyanonaphthaleneHCID 10942334Sodium Methoxide

生成物 1

HCID 178508665HCID 178508665、化合物収率 66%

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

In 2.5 moles of 2,3-dicyanonaphthalene, 0.075 mole of sodium methoxide and 1 liter of methanol, an ammonia gas was flowed with a suitable flow rate for 40 minutes. Then, the reaction solution was refluxed with heating while flowing the ammonia gas for 4 hours. After cooling, the product was filtered, and recrystallized from a mixed solvent of methanol/ether to yield yellow 1,3-diiminobenz(f)isoindoline in 66% yield.

後処理

  1. temperatureThen, the reaction solution was refluxed
  2. temperaturewith heating
  3. customfor 4 hours
  4. temperatureAfter cooling
  5. filtrationthe product was filtered
  6. customrecrystallized from a mixed solvent of methanol/ether

出典と根拠

ORDレコード
ord-e8ca792a0c1948b99e9860316712c124
出典データセット
uspto-grants-1992_01
特許番号
US05081236

関連ノート

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