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Dimethyl pyridine-3,5-dicarboxylate → Dimethyl piperidine-3,5-dicarboxylate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dimethyl pyridine-3,5-dicarboxylate | HCID 78339 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | Dimethyl piperidine-3,5-dicarboxylate | HCID 49761012 | — |
反応手順
Pyridine-3,5-dicarboxylic acid dimethyl ester (5.3 g, 27 mmol) and Rh/PtO2 (0.5 g) in MeOH (200 mL) are stirred under hydrogen overnight. The resulting mixture is filtered and the solvents are evaporated to leave a brown oil. MS (LC-MS): 202 [M+H]+
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08129411B2 |
| 出典データセット | uspto-grants-2012_03 |
| ORD ID | ord-057beef6e5814756bac2e2e621de65ab |
| 出典メモ | uspto-grants-2012_03 |