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Hydrazine → (3,4-diaMinophenyl)(Morpholino)Methanone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrazine | HCID 9321 | — |
| 反応物 | Sodium borohydride | HCID 4311764 | — |
| 反応物 | 2-Nitro-4-morpholinocarbonylaniline | HCID 20553752 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | (3,4-diaMinophenyl)(Morpholino)Methanone | HCID 22411123 | — |
反応手順
A solution of 0.14 g of ferrous sulfate heptahydrate in 15 ml of methanol is treated under nitrogen with 0.02 g of sodium borohydride. After 5 minutes, 2.5 g of 2-nitro-4-morpholinocarbonylaniline (as prepared in Example XXXIX) and 1 ml 64% hydrazine are added. The mixture is refluxed until reduction is complete (~4-6 hours) to afford 1,2-diamino-4-morpholinocarbonylbenzene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04312873 |
| 出典データセット | uspto-grants-1982_01 |
| ORD ID | ord-a334c2564d384db1ac4a3b280edab83a |
| 出典メモ | uspto-grants-1982_01 |