Water → 1-Nonyn-4-one

HRID 1106295ノート

反応式

HRID 1106295 の反応式
[CH:1]#[C:2][CH2:3][CH:4]([OH:10])[CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].CC(C)=O.OS(O)(=O)=O.O=[Cr](=O)=O.CCCCCC.O>CC(C)=O>[CH:1]#[C:2][CH2:3][C:4](=[O:10])[CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

参加物

6

反応物 4

HCID 962WaterHCID 8058HexaneHCID 109863221-Nonyn-4-olHCID 131709961Jones' reagent

生成物 1

HCID 205539671-Nonyn-4-one

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

A solution of 14 g of 1-nonyn-4-ol in 100 ml of acetone is cooled to 0° and treated dropwise with 70 ml of 2.67 molar Jones reagent with stirring. The reaction mixture is poured into a mixture of hexane and water, the organic layer is separated and washed with water, dried over sodium sulfate, stripped of solvent, and the residue distilled to give the title product.

後処理

  1. customthe organic layer is separated
  2. washwashed with water
  3. dry with materialdried over sodium sulfate
  4. distillationthe residue distilled

出典と根拠

ORDレコード
ord-fdf6124e36594f11b8fdd3d79d68d91a
出典データセット
uspto-grants-1982_01
特許番号
US04312994

反応ノート

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