2-Benzylbenzaldehyde → o-Benzylbenzoic acid

HRID 1106841

反応式

HRID 1106841 の反応式
[CH2:1]([C:8]1[CH:15]=[CH:14][CH:13]=[CH:12][C:9]=1[CH:10]=[O:11])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Br-].[C:17]([C:20]1[CH:46]=[CH:45][C:23]([CH2:24][CH2:25][P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=[CH:22][CH:21]=1)([OH:19])=[O:18]>>[CH2:1]([C:8]1[CH:15]=[CH:14][CH:13]=[CH:12][C:9]=1[CH2:10][CH:25]=[CH:24][C:23]1[CH:45]=[CH:46][C:20]([C:17]([OH:19])=[O:18])=[CH:21][CH:22]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:1]([C:8]1[CH:15]=[CH:14][CH:13]=[CH:12][C:9]=1[CH:10]=[O:11])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1.[CH2:1]([C:8]1[CH:15]=[CH:14][CH:13]=[CH:12][C:9]=1[C:10]([OH:18])=[O:11])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

参加物

5

反応物 2

HCID 100129102-BenzylbenzaldehydeHCID 226755274-Carboxyphenethyltriphenylphosphonium bromide

生成物 3

HCID 11924o-Benzylbenzoic acidHCID 100129102-BenzylbenzaldehydeHCID 544026144-[3-(2-Benzylphenyl)prop-1-enyl]benzoic acid

実験手順

4-[3-(2-Benzylphenyl)prop-1-enyl]benzoic acid was prepared by reaction of 2-benzylbenzaldehyde with 4-carboxyphenethyltriphenylphosphonium bromide using a similar method to that of example 33(B) to give a gum. [2-Benzylbenzaldehyde (an oil) was obtained from 2-benzylbenzoic acid using a similar method to that of example 33(A)].

後処理

  1. customto give a gum

出典と根拠

ORDレコード
ord-db1cf34c36be4a84bb1f4b7656331783
出典データセット
uspto-grants-2000_05
特許番号
US06057345

関連ノート

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