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Methanol → Phthalide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methanol | HCID 887 | — |
| 反応物 | Dimethyl Phthalate | HCID 8554 | — |
| 反応物 | Triethylmethylammonium | HCID 70440 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | Phthalide | HCID 6885 | 82% |
| 生成物 | N-Methoxymethyl-N-methylformamide | HCID 560292 | 64% |
反応手順
In an electrolytic cell as used in Example 1, 2.56 mol of dimethyl phthalate, 750 g of methanol, 1225 g of dimethylformamide (DMF) and 25 g of triethylmethylammonium methosulfate were subjected to electrolysis at 5 A and 50° C. for 6.9 h. 4.1 mol (current yield: 64%) of N-methoxymethyl-N-methylformamide were formed besides 2.1 mol of phthalide (material yield: 82%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06063256 |
| 出典データセット | uspto-grants-2000_05 |
| ORD ID | ord-8af5f26eca97411f88a7c1b01423c9d6 |
| 出典メモ | uspto-grants-2000_05 |