1-(Hexyloxy)-2-nitrobenzene → 2-(Hexyloxy)aniline

HRID 1110429ノート

反応式

HRID 1110429 の反応式
[CH2:1]([O:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[N+:14]([O-])=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[H][H]>CO.[Ni]>[CH2:1]([O:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[NH2:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

参加物

5

反応物 2

HCID 150681131-(Hexyloxy)-2-nitrobenzeneHCID 178418361HCID 178418361、化合物2 回

生成物 1

HCID 159374522-(Hexyloxy)aniline

試薬・触媒・溶媒 2

HCID 935Nickel触媒HCID 887Methanol溶媒

実験手順

1-(Hexyloxy)-2-nitrobenzene, 61.28 g (0.27 mol) is dissolved in 700 ml of methanol, 3 g Raney nickel is added and the mixture exposed to hydrogen gas until the required amount of hydrogen is absorbed. The methanol solution is filtered and concentrated in vacuo and the residue distilled to give 50 g of 2-(hexyloxy)benzenamine; bp 145°-148° C. at 4 mm.

後処理

  1. customis absorbed
  2. filtrationThe methanol solution is filtered
  3. concentrationconcentrated in vacuo
  4. distillationthe residue distilled

出典と根拠

ORDレコード
ord-b65654df64f84755832fadaf785add3c
出典データセット
uspto-grants-1990_12
特許番号
US04975456

反応ノート

読み込み中…