Carbon Disulfide → HCID 22766681、化合物
反応式
[C:1](=[S:3])=[S:2].[C:4]1([CH:10]2[O:14][CH:13]([C:15]([Cl:18])([Cl:17])[Cl:16])[NH:12][CH2:11]2)[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[CH2:19]([N:21]([CH2:24][CH3:25])[CH2:22][CH3:23])[CH3:20]>>[C:4]1([CH:10]2[O:14][CH:13]([C:15]([Cl:18])([Cl:17])[Cl:16])[N:12]([C:1]([S-:3])=[S:2])[CH2:11]2)[CH:5]=[CH:6][CH:7]=[CH:8][CH:9]=1.[CH2:19]([NH+:21]([CH2:24][CH3:25])[CH2:22][CH3:23])[CH3:20]参加物
4
実験手順
A solution of 355.6g (3.56 moles) triethylamine, 203.6 g (2.68 moles) carbon disulfide, and 474 g (1.78 moles) 5-phenyl-2-trichloromethyloxazolidine (prepared from 2-amino-1-phenyl-ethanol and chloral; m.p. 67°-9°) was stirred for nine days at ambient temperatures. The solution was removed of volatiles under reduced pressures to leave a residual viscous oil which was extracted with ethyl ether (10 × 200 ml). The combined ether extracts were removed of solvent under reduced pressures to yield 330 g of the crude, liquid triethylammonium 5-phenyl-2-trichloromethyl-3-oxazolidinecarbodithioate.