1,6-Hexanediamine, N1,N6-diethyl- → N,N'-(1,6-hexylene)-bis[N-ethyl-2-hydroxyundecylamine]

反応式

[CH2:1]1[O:12][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH2:13]([NH:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][NH:22][CH2:23][CH3:24])[CH3:14]>>[CH2:16]([N:15]([CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:13][CH3:14])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][N:22]([CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:23][CH3:24]

参加物

反応物 2

HCID 831321,6-Hexanediamine, N1,N6-diethyl-

HCID 5377372-Nonyloxirane

生成物 1

HCID 21332439N,N'-(1,6-hexylene)-bis[N-ethyl-2-hydroxyundecylamine]

実験手順

Condensation of 1-undecene oxide and N,N'-diethylhexamethylenediamine affords N,N'-(1,6-hexylene)-bis[N-ethyl-2-hydroxyundecylamine] (I: R = CH3 (CH2)8, R' = CH3CH2, X = (CH2)6, Z = H).

出典と根拠

ORDレコード: ord-a3c0d5d672c540d6a252d2fa64da3908
出典データセット: uspto-grants-1978_10
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04119668

反応ノート

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