Hydrogen Peroxide → HCID 22765156、化合物

HRID 1112130ノート

反応式

HRID 1112130 の反応式
[Cl:1][CH2:2][CH2:3][S:4]([CH2:7][CH2:8][C:9]([NH:11][CH2:12][CH2:13][S:14][CH:15]=[CH2:16])=[O:10])(=[O:6])=[O:5].[OH:17]O>C(O)(=O)C>[Cl:1][CH2:2][CH2:3][S:4]([CH2:7][CH2:8][C:9]([NH:11][CH2:12][CH2:13][S:14]([CH:15]=[CH2:16])=[O:17])=[O:10])(=[O:5])=[O:6]

参加物

4

反応物 2

HCID 784Hydrogen PeroxideHCID 227651493-(2-Chloroethanesulfonyl)-N-[2-(ethenylsulfanyl)ethyl]propanamide

生成物 1

HCID 22765156HCID 22765156、化合物

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒2 回

実験手順

A suspension of 6 g Intermediate 2 in 25 ml acetic acid was treated at 20° C. with 2.5 ml of 30 % hydrogen peroxide and 3 ml acetic acid. After 2 hours the solution was evaporated and the residue stirred with ether. The solid was filtered, dried and recrystallised from ethanol-petrolether. Yield 4.85 g; Mp. 108° to 109° C.

後処理

  1. customAfter 2 hours the solution was evaporated
  2. filtrationThe solid was filtered
  3. customdried
  4. customrecrystallised from ethanol-petrolether

出典と根拠

ORDレコード
ord-e459a77a6f2043d4b7b9f1eb0f6bbedb
出典データセット
uspto-grants-1978_10
特許番号
US04120898

反応ノート

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