Dimethylformamide → HCID 22765157、化合物

HRID 1112131ノート

反応式

HRID 1112131 の反応式
C(N(CC)CC)C.Cl[CH2:9][CH2:10][S:11]([CH2:14][CH2:15][C:16]([NH:18][CH2:19][CH2:20][S:21][CH:22]=[CH2:23])=[O:17])(=[O:13])=[O:12].CN(C)C=[O:27]>>[CH:10]([S:11]([CH2:14][CH2:15][C:16]([NH:18][CH2:19][CH2:20][S:21]([CH:22]=[CH2:23])=[O:27])=[O:17])(=[O:13])=[O:12])=[CH2:9]

参加物

4

反応物 3

HCID 6228DimethylformamideHCID 8471TriethylamineHCID 227651493-(2-Chloroethanesulfonyl)-N-[2-(ethenylsulfanyl)ethyl]propanamide

生成物 1

HCID 22765157HCID 22765157、化合物

実験手順

0.8 g Triethylamine was added to a solution of 2.0 g Intermediate 2 in 10 ml dimethylformamide. After stirring 1 hour the mixture was filtered and the filtrate evaporated. The residue was recrystallised form ethyl acetate and then from dichloromethanepetrolether. Yield 1.1 g; Mp. 93° C.

後処理

  1. filtrationwas filtered
  2. customthe filtrate evaporated
  3. customThe residue was recrystallised form ethyl acetate

出典と根拠

ORDレコード
ord-4b5f9f2540a346feb6e9abd33c727aa9
出典データセット
uspto-grants-1978_10
特許番号
US04120898

反応ノート

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