Hydrogen Peroxide → 77456-46-3

HRID 1155067ノート

反応式

HRID 1155067 の反応式
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([C:9]2[NH:17][C:16]3[C:11](=[N:12][CH:13]=[N:14][CH:15]=3)[N:10]=2)=[C:5]([O:18][CH2:19][CH2:20][S:21][CH3:22])[CH:4]=1.OO.C(=O)([O-])[O-:26].[K+].[K+]>C(O)(=O)C.O>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([C:9]2[NH:17][C:16]3[C:11](=[N:12][CH:13]=[N:14][CH:15]=3)[N:10]=2)=[C:5]([O:18][CH2:19][CH2:20][S:21]([CH3:22])=[O:26])[CH:4]=1

参加物

6

反応物 3

HCID 784Hydrogen PeroxideHCID 11430Potassium CarbonateHCID 30599141H-Purine, 8-(4-methoxy-2-(2-(methylthio)ethoxy)phenyl)-

生成物 1

HCID 305991577456-46-3

試薬・触媒・溶媒 2

HCID 176Acetic Acid溶媒HCID 962Water溶媒

実験手順

One gram of 8-[4-methoxy-2-(2-methylmercapto-ethoxy)phenyl]purine was dissolved in 10 ml of glacial acetic acid and mixed with 0.5 ml of 30% hydrogen peroxide. After standing for 3.5 hours at room temperature, the reaction mixture was diluted with water and made alkaline by means of potassium carbonate. The precipitate was recrystallized from isopropanol/ethanol in a volume ratio of 1:1.

後処理

  1. customThe precipitate was recrystallized from isopropanol/ethanol in a volume ratio of 1:1

出典と根拠

ORDレコード
ord-04319949ba4f417380491cc005a4805d
出典データセット
uspto-grants-1981_11
特許番号
US04299834

反応ノート

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