化工社化工社 化学情報印刷レポート · 研究参考用
2-Heptanone → 2-Heptanone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Heptanone | HCID 8051 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | 2-Heptanone | HCID 8051 | — |
| 生成物 | 2-Heptanol | HCID 10976 | — |
反応手順
Operating under the conditions of Example 1, 1 millimol of 2-heptanone in toluene (1 ml of a 1M soln.) is reacted with 0.375 millimol of Ca[AlH2 (OCH2CH2OCH3)2 ]2 in toluene (1.78 ml of a 0.21M soln.) during 30 mins. at room temperature. After treating the reaction mixture according to the procedure of Example 1, the resultant toluene solution is gaschromatographically analyzed. The yield of 2-heptanol, the result of the reduction of 2-heptanone, is quantitative.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04299986 |
| 出典データセット | uspto-grants-1981_11 |
| ORD ID | ord-5c29ef634ca14ab7a590912e3ad00693 |
| 出典メモ | uspto-grants-1981_11 |