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Carbon Dioxide → Triphenylphosphane dichloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Carbon Dioxide | HCID 280 | — |
| 反応物 | Triphenylphosphine Oxide | HCID 13097 | — |
| 反応物 | Oxalyl chloride | HCID 65578 | — |
| 反応物 | HCID 178418416 | HCID 178418416 | — |
| 溶媒 | Chlorobenzene | HCID 7964 | — |
| 生成物 | Triphenylphosphane dichloride | HCID 13797396 | 200% |
反応手順
In Example 1, 3.36 g (12 millimoles) of triphenylphosphine oxide and 1.54 g (12 millimoles) of oxalyl chloride were dissolved in 50 ml of monochlorobenzene, and the solution was left standing until the evolution of carbon monoxide and carbon dioxide from the solution was completed. A solution of 12 millimoles of triphenylphosphine dichloride in 50 ml of monochlorobenzene was obtained. That is, the conversion of triphenylphosphine oxide to triphenylphosphine dichloride was effected stoichiometrically.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04301301 |
| 出典データセット | uspto-grants-1981_11 |
| ORD ID | ord-85e2e41d84d5448dbd7d0bf27f7e2d13 |
| 出典メモ | uspto-grants-1981_11 |