Hexane → HCID 178511346、化合物

HRID 1155647

反応式

HRID 1155647 の反応式
[NH2:1][CH2:2][CH2:3][NH:4][CH2:5][CH2:6][NH:7][CH2:8][CH2:9][NH:10][CH2:11][CH2:12][NH2:13].C1([CH:20]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[C:21](O)=[O:22])C=CC=CC=1.[CH3:40][CH2:41][CH2:42][CH2:43][CH2:44][CH3:45]>>[C:42]1([CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:20][C:21]([NH-:1])=[O:22])[CH:41]=[CH:40][CH:45]=[CH:44][CH:43]=1.[C:42]1([CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:20][C:21]([NH-:1])=[O:22])[CH:41]=[CH:40][CH:45]=[CH:44][CH:43]=1.[C:42]1([CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:20][C:21]([NH-:1])=[O:22])[CH:41]=[CH:40][CH:45]=[CH:44][CH:43]=1.[NH2:13][CH2:12][CH2:11][NH:10][CH2:9][CH2:8][NH:7][CH2:6][CH2:5][NH:4][CH2:3][CH2:2][NH2:1]

参加物

4

反応物 3

HCID 8058Hexane2 回HCID 8197TetraethylenepentamineHCID 220152372-Phenyloctadecanoic acid2 回

生成物 1

HCID 178511346HCID 178511346、化合物

反応条件

温度
175 °C

実験手順

Into a 300 ml reaction flask equipped with a thermometer, an agitator and an addition funnel, 6 g (0.03 mole) tetraethylenepentamine was added and heated to 70°-75° C. with agitation. From the addition funnel, 32.4 g (0.09 mole) phenylstearic acid was added over 10 minutes. To insure complete addition of phenylstearic acid, 15-20 ml hexane was added to the addition funnel and thence into the reaction mixture after hexane was allowed to evaporate away, the contents of the flask was placed under reduced pressure and heated to 175° C. with agitation. Heating was continued at 175° C. for 2 hours allowing the condensation water to distill off. The product, tetraethylenepentamine tris(phenylstearoylamide) was viscous, amber colored liquid.

後処理

  1. customInto a 300 ml reaction flask
  2. customequipped with a thermometer
  3. temperatureheated to 70°-75° C. with agitation
  4. customto evaporate away
  5. temperatureHeating
  6. customthe condensation water
  7. distillationto distill off

出典と根拠

ORDレコード
ord-f8fe0ca93e4d48659534eb6651c3c68e
出典データセット
uspto-grants-1982_06
特許番号
US04332737

関連ノート

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