Triethylamine → Methylthiomethyl Geranate

HRID 1155730ノート

反応式

HRID 1155730 の反応式
[C:1]([OH:12])(=[O:11])/[CH:2]=[C:3](/[CH2:5][CH2:6][CH:7]=[C:8]([CH3:10])[CH3:9])\[CH3:4].[CH3:13][S:14][CH2:15]Cl.C(N(CC)CC)C>>[C:1]([O:12][CH2:13][S:14][CH3:15])(=[O:11])/[CH:2]=[C:3](/[CH2:5][CH2:6][CH:7]=[C:8]([CH3:9])[CH3:10])\[CH3:4]

参加物

4

反応物 3

HCID 8471TriethylamineHCID 16916Chloromethyl methyl sulfideHCID 5275520Geranic acid

生成物 1

HCID 86738396Methylthiomethyl Geranate

実験手順

This product was prepared according to the procedure described in Example 1, by reacting geranic acid with chloromethyl methyl sulfide in the presence of one equivalent of triethylamine; b.p. 111°-112° C./2 mm Hg, n20 1.4912.

後処理

  1. customThis product was prepared

出典と根拠

ORDレコード
ord-66067993e62146ceba9ba1e86f7129de
出典データセット
uspto-grants-1982_06
特許番号
US04332829

反応ノート

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