化工社化工社 化学情報印刷レポート · 研究参考用
Benzoic Acid → Benzoic acid, 4-(1,1-dimethylethyl)-, hydrazide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzoic Acid | HCID 243 | — |
| 反応物 | 4-tert-Butylbenzoic acid | HCID 7403 | — |
| 反応物 | Hydrazine | HCID 9321 | — |
| 反応物 | 2-Hydroxy-1-naphthaldehyde-o-aminobenzoyl hydrazone | HCID 3084951 | — |
| 生成物 | Benzoic acid, 4-(1,1-dimethylethyl)-, hydrazide | HCID 123513 | — |
反応手順
The particularly preferred substituted aromatic hydrazone 2-hydroxy-1-naphthaldehyde-p-(t-butyl)-benzoyl hydrazone is prepared in a manner similar to the preparation of 2-hydroxy-1-naphthaldehyde-o-aminobenzoyl hydrazone, Equations (1) through (3) above. Since the ester of p-(t-butyl)-benzoic acid is not available the preparation of this hydrazone requires the additional step of esterification of the benzoic acid. The ester of p-(t-butyl)-benzoic acid is reacted with hydrazine to produce p-(t-butyl)-benzhydrazide. This hydrazide is then reacted with 2-hydroxy-1-naphthaldehyde to yield 2-hydroxy-1-naphthaldehyde-p-(t-butyl)-benzoyl hydrazone.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04334015 |
| 出典データセット | uspto-grants-1982_06 |
| ORD ID | ord-803e2f836c27437cbbaca2d01beb8325 |
| 出典メモ | uspto-grants-1982_06 |