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HRID 1156090作成日:2026年10月26日

Benzoic Acid → Benzoic acid, 4-(1,1-dimethylethyl)-, hydrazide

https://huagongshe.com/reaction/1156090

反応式

関与物質

役割名称HCID仕込み量
反応物Benzoic AcidHCID 243—
反応物4-tert-Butylbenzoic acidHCID 7403—
反応物HydrazineHCID 9321—
反応物2-Hydroxy-1-naphthaldehyde-o-aminobenzoyl hydrazoneHCID 3084951—
生成物Benzoic acid, 4-(1,1-dimethylethyl)-, hydrazideHCID 123513—

反応手順

The particularly preferred substituted aromatic hydrazone 2-hydroxy-1-naphthaldehyde-p-(t-butyl)-benzoyl hydrazone is prepared in a manner similar to the preparation of 2-hydroxy-1-naphthaldehyde-o-aminobenzoyl hydrazone, Equations (1) through (3) above. Since the ester of p-(t-butyl)-benzoic acid is not available the preparation of this hydrazone requires the additional step of esterification of the benzoic acid. The ester of p-(t-butyl)-benzoic acid is reacted with hydrazine to produce p-(t-butyl)-benzhydrazide. This hydrazide is then reacted with 2-hydroxy-1-naphthaldehyde to yield 2-hydroxy-1-naphthaldehyde-p-(t-butyl)-benzoyl hydrazone.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US04334015
出典データセットuspto-grants-1982_06
ORD IDord-803e2f836c27437cbbaca2d01beb8325
出典メモuspto-grants-1982_06