Hydrochloric Acid → 2-(p-Biphenylyl)-2-penten-4-one

HRID 1156271

反応式

HRID 1156271 の反応式
[C:1]1([C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[C:7](O)([CH:9]=[C:10]=[CH2:11])[CH3:8].Cl.C[OH:21]>>[C:1]1([C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[C:7](=[CH:9][C:10](=[O:21])[CH3:11])[CH3:8]

参加物

4

反応物 3

HCID 313Hydrochloric AcidHCID 887MethanolHCID 867348952-(p-Biphenylyl)-3,4-pentadien-2-ol

生成物 1

HCID 545652342-(p-Biphenylyl)-2-penten-4-one

実験手順

To a solution of 10 g. of 2-(p-biphenylyl)-3,4-pentadien-2-ol in 200 ml. of anhydrous methanol is added 3 ml. of concentrated hydrochloric acid. The resulting mixture is stirred at room temperature for 3 hours and then in an ice bath for 2 hours. Solids form and are filtered off and recrystallized from pentane to obtain 2-(p-biphenylyl)-2-penten-4-one.

後処理

  1. waitin an ice bath for 2 hours
  2. filtrationSolids form and are filtered off
  3. customrecrystallized from pentane

出典と根拠

ORDレコード
ord-6d951510b40245b3a50d1ef57549775f
出典データセット
uspto-grants-1982_06
特許番号
US04335124

関連ノート

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