Carbon Tetrachloride → 2-CHLORO-1-(PHENYLSULFONYL)ETHYL p-BROMOPHENYL SULFIDE

HRID 1156376ノート

反応式

HRID 1156376 の反応式
[CH:1]([S:3]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)(=[O:5])=[O:4])=[CH2:2].[Br:12][C:13]1[CH:18]=[CH:17][C:16]([S:19]Cl)=[CH:15][CH:14]=1.C(Cl)(Cl)(Cl)[Cl:22]>C(O)(=O)C>[Br:12][C:13]1[CH:18]=[CH:17][C:16]([S:19][CH:1]([S:3]([C:6]2[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=2)(=[O:4])=[O:5])[CH2:2][Cl:22])=[CH:15][CH:14]=1

参加物

5

反応物 3

HCID 5943Carbon TetrachlorideHCID 79664Phenyl vinyl sulfoneHCID 11746248Benzenesulfenyl chloride, 4-bromo-

生成物 1

HCID 130447982-CHLORO-1-(PHENYLSULFONYL)ETHYL p-BROMOPHENYL SULFIDE

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

実験手順

A solution of 24.8 g (0.147 mole) of phenyl vinyl sulfone in 50 ml of carbon tetrachloride and 25 ml of glacial acetic acid at 28° was treated with 32.8 g (0.146 mole) of p-bromobenzenesulfenyl chloride. A 4° exotherm occurred. The reaction mixture was allowed to stand for 72 hours. The solvent was removed by evaporation at reduced pressure. The residue was recrystallized from 50 ml of benzene to give colorless needles, m.p. 97.5°-98.5°.

後処理

  1. customA 4°
  2. customThe solvent was removed by evaporation at reduced pressure
  3. customThe residue was recrystallized from 50 ml of benzene
  4. customto give colorless needles, m.p. 97.5°-98.5°

出典と根拠

ORDレコード
ord-19000674233748c59ed3c02bd7ac48e6
出典データセット
uspto-grants-1982_06
特許番号
US04335142

反応ノート

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