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Ammonia → 4-Amino-3,5,6-trichloro-2-(trichloromethyl)pyridine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ammonia | HCID 222 | — |
| 反応物 | Picloram | HCID 15965 | — |
| 反応物 | Pyridine, 2,3,4,5-tetrachloro-6-(trichloromethyl)- | HCID 70811 | — |
| 生成物 | 4-Amino-3,5,6-trichloro-2-(trichloromethyl)pyridine | HCID 138402 | — |
反応手順
It is known that 4-amino-3,5,6-trichloropicolinic acid is prepared by a two-step method where heptachloro-2-picoline is aminated with anhydrous liquid ammonia to form 4-amino-hexachloro-2-picoline, an intermediate product that is isolated, and which is in turn hydrolyzed with sulfuric acid to form 4-amino-3,5,6-trichloropicolinic acid. See, for example, Russian Pat. No. 445,662.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04336384 |
| 出典データセット | uspto-grants-1982_06 |
| ORD ID | ord-da9c886eb31644f2b2de86976b770d90 |
| 出典メモ | uspto-grants-1982_06 |