Phenol → Urea Urethane

HRID 1158184

反応式

HRID 1158184 の反応式
CC1C=CC([N:8]=[C:9]=[O:10])=CC=1[N:11]=[C:12]=[O:13].C1C([NH2:20])=CC=C(S(C2C=CC(N)=CC=2)(=O)=O)C=1.[C:31]1([OH:37])C=CC=C[CH:32]=1>CCC(C)=O.C(N(CC)CC)C>[NH2:20][C:12]([NH2:11])=[O:13].[NH2:8][C:9]([O:37][CH2:31][CH3:32])=[O:10]

参加物

6

反応物 3

HCID 996PhenolHCID 2955DapsoneHCID 11443Toluene 2,4-Diisocyanate

生成物 1

HCID 21585015Urea Urethane収率 542%

試薬・触媒・溶媒 2

HCID 8471Triethylamine触媒HCID 6569Methyl Ethyl Ketone溶媒

反応条件

温度
50 °C

実験手順

To 31.5 g of 2,4-toluene diisocyanate was added dropwise a solution of 21.5 g of 4,4′-diaminodiphenyl sulfone in 60 mL of MEK at 70° C. with stirring at 300 to 500 rpm over a period of 4 hours, and the reaction was carried out for another 4 hours to obtain a white viscous slurry reaction mixture. Then, the reaction mixture was cooled to 50° C., and 17.1 g of phenol was poured into the reaction mixture to be dissolved therein, after which 0.015 g of triethylamine was added thereto as a catalyst, and the reaction was carried out for 4 hours to obtain a yellow, transparent and viscous reaction mixture. This reaction mixture was freed of the solvent and concentrated under reduced pressure to be solidified, after which the resulting solid was ground and then dried overnight in a vacuum to obtain about 70 g of a urea-urethane composition as light-yellow powder.

後処理

  1. waitthe reaction was carried out for another 4 hours
  2. customto obtain
  3. customa white viscous slurry reaction mixture
  4. dissolutionto be dissolved
  5. waitas a catalyst, and the reaction was carried out for 4 hours
  6. customto obtain a yellow, transparent and viscous reaction mixture
  7. concentrationconcentrated under reduced pressure
  8. customdried overnight in a vacuum

出典と根拠

ORDレコード
ord-260d64d01db240b69b6d579f3a8856c8
出典データセット
uspto-grants-2010_10
特許番号
US07807738B2

関連ノート

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