関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Vinyltrichlorosilane | HCID 6413 | — |
| 反応物 | Dichlorosilane | HCID 61330 | — |
| 触媒 | Dicobalt Octacarbonyl (stabilized with 1-5% Hexane) | HCID 25049 | — |
| 生成物 | 1,1,1,4,4-Pentachloro-1,4-disilabutane | HCID 101929494 | 108% |
反応手順
Vinyltrichlorosilane (68.8 g, 426 mmol) and cobalt octacarbonyl (700 mg) were placed in a 100 mL rb flask and cooled in an ice bath to 0° C. Dichlorosilane (bp. 8° C., 44.3 g, 439 mmol) was then condensed into the flask, The system was allowed to warm up to room temperature during night. Distillation at 60 . . . 62° C./8 mbar gave 1,1,1,4,4-Pentachloro-1,4-disilabutane (120.8 g, 460 mmol) in 93% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07833820B2 |
|---|
| 出典データセット | uspto-grants-2010_11 |
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| ORD ID | ord-7cb81af7f20344d7848b45a4dcfc5c70 |
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| 出典メモ | uspto-grants-2010_11 |
|---|
