Vinyltrichlorosilane → HCID 13463725、化合物

HRID 1172049

反応式

HRID 1172049 の反応式
[CH:1]([Si:3]([Cl:6])([Cl:5])[Cl:4])=[CH2:2].[Cl:7][Si:8]([Cl:15])([Cl:14])[CH2:9][CH2:10][SiH:11]([Cl:13])[Cl:12]>>[Cl:4][Si:3]([Cl:6])([Cl:5])[CH2:1][CH2:2][Si:11]([Cl:13])([Cl:12])[CH2:10][CH2:9][Si:8]([Cl:15])([Cl:14])[Cl:7]

参加物

3

反応物 2

HCID 6413VinyltrichlorosilaneHCID 1019294941,1,1,4,4-Pentachloro-1,4-disilabutane

生成物 1

HCID 13463725HCID 13463725、化合物

実験手順

Vinyltrichlorosilane (16.8 g, 104 mmol) was heated to 60° C. and 100 μL 10% H2PtCl6/IPA-solution was added. 1,1,1,4,4-pentachloro-1,4-disilabutane (20.4 g, 77.7 mmol) was added slowly during 20 min so that the temperature did not exceed 100° C. The reaction was allowed to proceed for 12 hours at 100° C., after which it was distilled under vacuum at 115-130° C./<1 mbar. The yield was 31.5 g (74.3 mmol, 96%).

後処理

  1. customdid not exceed 100° C
  2. distillationafter which it was distilled under vacuum at 115-130° C./<1 mbar

出典と根拠

ORDレコード
ord-ecc149b50f6746d4a9fec7163b23f264
出典データセット
uspto-grants-2010_11
特許番号
US07833820B2

関連ノート

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