Glycerol → Tris(N-(1-oxotetradecyl)-L-glutamato(2-))dialuminium

HRID 1178165

反応式

HRID 1178165 の反応式
[C:1]([NH:16][C@H:17]([C:23]([O-:25])=[O:24])[CH2:18][CH2:19][C:20]([O-:22])=[O:21])(=[O:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[Na+].[Na+].[Cl-].[Al+3:29].[Cl-].[Cl-].OCC(CO)O>O>[C:1]([NH:16][C@H:17]([C:23]([O-:25])=[O:24])[CH2:18][CH2:19][C:20]([O-:22])=[O:21])(=[O:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[Al+3:29].[C:1]([NH:16][C@H:17]([C:23]([O-:25])=[O:24])[CH2:18][CH2:19][C:20]([O-:22])=[O:21])(=[O:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[C:1]([NH:16][C@H:17]([C:23]([O-:25])=[O:24])[CH2:18][CH2:19][C:20]([O-:22])=[O:21])(=[O:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[Al+3:29]

参加物

5

反応物 3

HCID 753GlycerolHCID 6451240Aluminum(III) ChlorideHCID 71587140Disodium myristoyl glutamate2 回

生成物 1

HCID 56843224Tris(N-(1-oxotetradecyl)-L-glutamato(2-))dialuminium

試薬・触媒・溶媒 1

HCID 962Water溶媒3 回

反応条件

温度
60 °C

実験手順

One hundred grams of sericite was added to 450 ml of water and mixed using a home type mixer until well dispersed. Four grams of sodium N-myristoyl-L-glutamate having an HLB value of 4, was dissolved in 50 ml of water heated at 60° C. then added to the above mixture and mixed for 10 minutes. While this was being stirred, 2 chemical equivalents of aluminum chloride aqueous solution, based on the sodium N-myristoyl-L-glutamate, was added dropwise. Four grams of glycerin having an HLB value of 20 was dissolved in 50 ml of water heated at 50° C. then added to the above mixture and mixed for 10 minutes. The product was filtered with suction using a Buchner funnel, followed by rinsing with purified water. The filter cake was then baked in an over for two hours after the filter cake reached a temperature of 100° C. to further dehydrate the filter cake. The cake was crushed and pulverized to a powder after cooling. This resulted in sericite pigment chemically immobilized with aluminum N-myristoyl-L-glutamate; the glycerin did not chemically immobilize itself to the pigment, but instead was washed away.

後処理

  1. additionmixed
  2. additionuntil well dispersed
  3. additionthen added to the above mixture
  4. additionmixed for 10 minutes
  5. additionwas added dropwise
  6. temperatureheated at 50° C.
  7. additionthen added to the above mixture
  8. additionmixed for 10 minutes
  9. filtrationThe product was filtered with suction
  10. washby rinsing with purified water
  11. customover for two hours
  12. customa temperature of 100° C.
  13. customThe cake was crushed
  14. temperatureafter cooling

出典と根拠

ORDレコード
ord-b72cd1d35c1045e7a17e33df30c82834
出典データセット
uspto-grants-2007_10
特許番号
US07276113B2

関連ノート

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