Triethylamine → HCID 58978005、化合物
反応式
[CH3:1][NH:2][CH2:3][CH2:4][NH:5][C:6](=[O:15])[O:7][CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.C(N(CC)CC)C.[CH3:23][S:24](Cl)(=[O:26])=[O:25]>C(Cl)Cl>[CH3:1][N:2]([S:24]([CH3:23])(=[O:26])=[O:25])[CH2:3][CH2:4][NH:5][C:6](=[O:15])[O:7][CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1参加物
5
実験手順
A solution of benzyl 2-(methylamino)ethylcarbamate (0.05 g, 0.24 mmol) in CH2Cl2 (5 mL was cooled to 6° C. and treated with triethylamine (0.1 mL, 0.72 mmol) and methanesulfonyl chloride (0.02 mL, 0.24 mmol). The reaction was warmed to room temperature and stirred overnight. The reaction was washed with 10% KHSO4, the organic layer was dried over Na2SO4, filtered and evaporated to give the product.
後処理
- washThe reaction was washed with 10% KHSO4
- dry with materialthe organic layer was dried over Na2SO4
- filtrationfiltered
- customevaporated
- customto give the product
出典と根拠
- ORDレコード
- ord-1f44ceecbd6d49deac0bc36acf6c1302
- 出典データセット
- uspto-grants-2007_10
- 特許番号
- US07279487B2
反応ノート
読み込み中…