Dibenzofuran → 2-Iododibenzofuran
反応式
[CH:1]1[C:9]2[C:8]3[CH:10]=[CH:11][CH:12]=[CH:13][C:7]=3[O:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.II.[I:16](O)(O)(O)(O)(O)=O.S(=O)(=O)(O)O>O.C(O)(=O)C>[I:16][C:2]1[CH:3]=[CH:4][C:5]2[O:6][C:7]3[CH:13]=[CH:12][CH:11]=[CH:10][C:8]=3[C:9]=2[CH:1]=1参加物
7
反応条件
- 温度
- 60 °C
実験手順
In a 500 mL three-neck flask was put a suspension of 8.4 g (50 mmol) of dibenzofuran, 6.2 g (25 mmol) of iodine, 5.7 g (25 mmol) of orthoperiodic acid, 150 mL of glacial acetic acid, 30 mL of water, and 500 μL of sulfuric acid, and the suspension was heated and stirred at 60° C. for 4.5 hours to cause a reaction.
後処理
- customIn a 500 mL three-neck flask was put
- temperaturethe suspension was heated
- customa reaction
出典と根拠
- ORDレコード
- ord-b9923b8b10374364ba78da49e7cf6de8
- 出典データセット
- uspto-grants-2014_03
- 特許番号
- US08664263B2
反応ノート
読み込み中…