Toluene → HCID 67034799、化合物
反応式
[CH3:1][Si:2]([CH3:11])([CH:9]=[CH2:10])[NH:3][Si:4]([CH3:8])([CH3:7])[CH:5]=[CH2:6].C([C:14]1([O:20][Si:21]([CH3:24])([CH3:23])[CH3:22])CCCCC1)#C.[C:25]1(C)[CH:30]=[CH:29]C=[CH:27][CH:26]=1>>[CH3:22][Si:21]([CH3:23])([CH3:24])[O:20][C:14]#[C:6][C:5]1([Si:4]([CH3:8])([CH3:7])[NH:3][Si:2]([CH3:1])([CH3:11])[CH:9]=[CH2:10])[CH2:29][CH2:30][CH2:25][CH2:26][CH2:27]1参加物
4
実験手順
As in reaction conditions of Example XIX Step 1, to 4.69 mL of toluene, the 0.02 g carbonylchlorohydridebis(triisopropylphosphine)ruthenium(II) was added, and the reaction was carried out between 2.29 g 1,1,3,3-tetramethyl-1,3-divinyldisilazane and 0.81 g 1-ethynyl-1-(trimethylsiloxy)cyclohexane. Raw 1-[(1-trimethylsiloxy-1-ethynyl)cyclohexyl]-1,1,3,3-tetramethyl-3-vinyldisilazane was obtained.
後処理
- customAs in reaction conditions of Example XIX Step 1