化工社化工社 化学情報印刷レポート · 研究参考用
Pentanal, 5,5-dimethoxy- → (E)-6-nitro-7-p-tolylhept-5-enal
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Pentanal, 5,5-dimethoxy- | HCID 170903 | — |
| 反応物 | 1-Methyl-4-(2-nitroethyl)benzene | HCID 11228988 | — |
| 溶媒 | Ethyl acetate hexane | HCID 21226206 | — |
| 生成物 | (E)-6-nitro-7-p-tolylhept-5-enal | HCID 58434561 | 35% |
反応手順
Prepared according to the general procedure B from 1-methyl-4-(2-nitroethyl)benzene 112f (24 mmol) and 5,5-dimethoxypentanal 131 (16 mmol) to provide the title compound as yellow oil (1.38 g, 35% yield) after silica gel chromatography (EtOAc/Hexane).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08680335B2 |
| 出典データセット | uspto-grants-2014_03 |
| ORD ID | ord-2d70649003f54a99891b9c95a32471c4 |
| 出典メモ | uspto-grants-2014_03 |