1-[4-(4-Methoxyphenyl)-4-methylpentyl]-3-phenoxybenzene → 1-Fluoro-4-[4-(4-methoxyphenyl)-4-methylpentyl]-2-phenoxybenzene

HRID 1194403ノート

反応式

HRID 1194403 の反応式
O(C1C=C(CCCC(C2C=CC(OC)=CC=2)(C)C)C=CC=1)C1C=CC=CC=1.[O:28]([C:35]1[CH:36]=[C:37]([CH2:42][CH:43]=[CH:44][C:45]([C:48]2[CH:53]=[CH:52][C:51]([O:54][CH3:55])=[CH:50][CH:49]=2)([CH3:47])[CH3:46])[CH:38]=[CH:39][C:40]=1[F:41])[C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1.O(C1C=C(C=CCC(C2C=CC(OC)=CC=2)(C)C)C=CC=1F)C1C=CC=CC=1>>[O:28]([C:35]1[CH:36]=[C:37]([CH2:42][CH2:43][CH2:44][C:45]([C:48]2[CH:53]=[CH:52][C:51]([O:54][CH3:55])=[CH:50][CH:49]=2)([CH3:46])[CH3:47])[CH:38]=[CH:39][C:40]=1[F:41])[C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1

参加物

4

反応物 3

HCID 135322971-[4-(4-Methoxyphenyl)-4-methylpentyl]-3-phenoxybenzeneHCID 54304426HCID 54304426、化合物HCID 54480050HCID 54480050、化合物

生成物 1

HCID 135564701-Fluoro-4-[4-(4-methoxyphenyl)-4-methylpentyl]-2-phenoxybenzene

実験手順

In the same manner as described in (2) of Synthesis Example 1, the mixture of 1-(3-phenoxy-4-fluorophenyl)-4-(4-methoxyphenyl)-4-methyl-2-pentene and 1-(3-phenoxy-4-fluorophenyl)-4-(4-methoxyphenyl)-4-methyl-1-pentene obtained according to the above (1) was treated to give quantiatively 1-(3-phenoxy-4-fluorophenyl)-4-(4-methoxyphenyl)-4-methylpentane.

後処理

  1. customobtained
  2. additionwas treated

出典と根拠

ORDレコード
ord-5e24dc05998243858c33fb886e15002c
出典データセット
uspto-grants-1989_03
特許番号
US04814340

反応ノート

読み込み中…