Acetic Acid → 2,6-Diacetoxynaphthalene

HRID 1194597ノート

反応式

HRID 1194597 の反応式
[OH:1][C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[C:7]([OH:12])[CH:8]=2)[CH:3]=1.[C:13](OC(=O)C)(=[O:15])[CH3:14].[C:20](O)(=[O:22])[CH3:21]>>[C:13]([O:1][C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[C:7]([O:12][C:20](=[O:22])[CH3:21])[CH:8]=2)[CH:3]=1)(=[O:15])[CH3:14]

参加物

4

反応物 3

HCID 176Acetic AcidHCID 7918Acetic AnhydrideHCID 935522,6-Dihydroxynaphthalene

生成物 1

HCID 5949302,6-Diacetoxynaphthalene

実験手順

In the same manner as in Example 7, 13.0 g of the thus obtained 2,6-dihydroxynaphthalene were acetylated with 5.9 g of acetic acid and 17.6 g of acetic anhydride to obtain 17.5 g of 2,6-diacetoxynaphthalene of the purity of 99.82% (by DSC).

出典と根拠

ORDレコード
ord-11ce63c237144196aba37e1d7754d260
出典データセット
uspto-grants-1989_03
特許番号
US04814521

反応ノート

読み込み中…