化工社化工社 化学情報印刷レポート · 研究参考用
(R)-(+)-1,1,1-trifluoro-2-octyl 4-benzyloxybenzoate → 4-hydroxybenzoic acid (R)-1-trifluoromethyl-heptyl ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | (R)-(+)-1,1,1-trifluoro-2-octyl 4-benzyloxybenzoate | HCID 22850730 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 4-hydroxybenzoic acid (R)-1-trifluoromethyl-heptyl ester | HCID 14549217 | — |
反応手順
The resulting ester compound and 0.13 g of 10% palladium-on-carbon were added to ethanol to conduct debenzylation in a hydrogen atmosphere to obtain 0.39 g of (R)-(+)-4-hydroxybenzoic acid 1-trifluoromethylheptyl ester ##STR7##
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05110497 |
| 出典データセット | uspto-grants-1992_05 |
| ORD ID | ord-21036450c4914879a77787c2a5666200 |
| 出典メモ | uspto-grants-1992_05 |