HCID 19819013、化合物 → HCID 19819021、化合物

HRID 1195239ノート

反応式

HRID 1195239 の反応式
[BrH:1].[CH:2]1([C:5]([CH:7]2[CH2:9][CH2:8]2)=[NH:6])[CH2:4][CH2:3]1>CS(C)=O>[Br-:1].[N+:6]12[CH2:9][CH2:8][CH2:7][C:5]=1[CH2:2][CH2:3][CH2:4]2

参加物

3

反応物 1

HCID 19819013HCID 19819013、化合物

生成物 1

HCID 19819021HCID 19819021、化合物収率 56%

試薬・触媒・溶媒 1

HCID 679Dimethyl Sulfoxide溶媒

反応条件

温度
100 °C

実験手順

A solution of dicyclopropylmethanimine hydrobromide (1.00 g, 5.26 mmol) in 6.0 ml of dimethyl sulfoxide was heated with stirring at 100° C. for 1 hour. The solvent was distilled out in vacuo and of isobutyl alcohol (8 ml) was added to the residue. Precipitated crystals was obtained and dried in vacuo to afford 0.56 g (Yield: 56%) of the desired compound.

後処理

  1. distillationThe solvent was distilled out in vacuo and of isobutyl alcohol (8 ml)
  2. additionwas added to the residue
  3. customPrecipitated crystals
  4. customwas obtained
  5. customdried in vacuo

出典と根拠

ORDレコード
ord-33811c3787354e279c0d15ff08a02205
出典データセット
uspto-grants-1992_05
特許番号
US05110945

反応ノート

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