Allylamine → 2,2,4-Trimethyl-1-allyl-1-aza-2-silacyclopentane

HRID 1195414

反応式

HRID 1195414 の反応式
Cl[Si:2]([CH3:9])([CH3:8])[CH2:3][CH:4]([CH3:7])[CH2:5]Cl.[CH2:10]([NH2:13])[CH:11]=[CH2:12]>>[CH3:8][Si:2]1([CH3:9])[CH2:3][CH:4]([CH3:7])[CH2:5][N:13]1[CH2:10][CH:11]=[CH2:12]

参加物

3

反応物 2

HCID 7853AllylamineHCID 86665Chloro(3-chloro-2-methylpropyl)dimethylsilane

生成物 1

HCID 191071842,2,4-Trimethyl-1-allyl-1-aza-2-silacyclopentane

実験手順

The 1,1,4-trimethyl-2-allyl-2-aza-silacyclopentane was prepared as follows. Chlorodimethyl(3-chloro-2-methylpropyl)silane (100 g, 0.54 mol) was slowly added to 211.73 g (3.71 mol, 6.87 eq) of undistilled allyl amine resulting in an exothermic reaction. This reaction mixture was stirred at room temperature for 15 hours, heated to reflux at atmospheric pressure for 72 hours, and heated to 120° C. under about 50 psig pressure for 16 hours. The following GC-MS ratios shown in Table II exemplified the reactions progression and the spectra observed were as shown.

後処理

  1. temperatureheated
  2. temperatureto reflux at atmospheric pressure for 72 hours
  3. temperatureheated to 120° C. under about 50 psig pressure for 16 hours

出典と根拠

ORDレコード
ord-9b8bfc6f7d57420e8384e81c6baefc56
出典データセット
uspto-grants-1992_05
特許番号
US05110967

関連ノート

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