Allyl isocyanate → 1-Allyl-3-(2,5-dichlorophenoxy) urea
反応式
[Cl:1][C:2]1[CH:9]=[CH:8][C:7]([Cl:10])=[CH:6][C:3]=1[O:4][NH2:5].[CH2:11]([N:14]=[C:15]=[O:16])[CH:12]=[CH2:13]>C1(C)C=CC=CC=1>[CH2:11]([NH:14][C:15]([NH:5][O:4][C:3]1[CH:6]=[C:7]([Cl:10])[CH:8]=[CH:9][C:2]=1[Cl:1])=[O:16])[CH:12]=[CH2:13]参加物
4
実験手順
5.34 g (30.0 mmoles) of 2,5-dichlorophenoxyamine was dissolved in 50 ml of toluene, and then 2.74 g (33.0 mmoles) of allyl isocyanate was added. The mixture was stirred at a temperature of from 25° to 30° C. for 12 hours. The crystals precipitated in the reaction solution were collected by filtration and washed with hexane, whereby, 3.96 g of the desired product was obtained as light yellow crystals (yield: 51%).
後処理
- customThe crystals precipitated in the reaction solution
- filtrationwere collected by filtration
- washwashed with hexane, whereby
出典と根拠
- ORDレコード
- ord-b4e8d7f9d8b84020a01ddabc163baa03
- 出典データセット
- uspto-grants-1992_05
- 特許番号
- US05112385
反応ノート
読み込み中…