Gallium, chlorodimethyl- → (3-Dimethylarsinopropyl)-dimethylgallium

HRID 1195612ノート

反応式

HRID 1195612 の反応式
[CH3:1][As:2]([CH3:7])[CH2:3][CH2:4][CH2:5]Cl.[Mg].[Cl-].[CH3:10][Ga+:11][CH3:12]>C(OCC)C>[CH3:1][As:2]([CH3:7])[CH2:3][CH2:4][CH2:5][Ga:11]([CH3:12])[CH3:10]

参加物

5

反応物 3

HCID 81329Gallium, chlorodimethyl-HCID 5462224MagnesiumHCID 85772197(3-Dimethylarsinopropyl)chloride

生成物 1

HCID 86745768(3-Dimethylarsinopropyl)-dimethylgallium

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒2 回

実験手順

5.47 g (30 mmol) of (3-dimethylarsinopropyl)chloride are added to 1.44 g (60 mmol) of magnesium chips in 100 ml of diethylether at 20° C., and then the mixture is heated under reflux for two hours. The solution is allowed to come to room temperature, 4.0 g (30 mmol) of dimethylgallium chloride in 50 ml of diethylether are added, and the solution is refluxed again for two hours. The working up is carried out analogously to Example 1. (3-Dimethylarsinopropyl)-dimethylgallium is obtained as a clear liquid with a B. p. of 86° C./0.01 mbar.

後処理

  1. temperaturethe mixture is heated
  2. temperatureunder reflux for two hours
  3. customto come to room temperature
  4. temperaturethe solution is refluxed again for two hours

出典と根拠

ORDレコード
ord-feae29b945f149c08903f457d17d58b0
出典データセット
uspto-grants-1992_05
特許番号
US05112432

反応ノート

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