Water → HCID 178517449、化合物

HRID 1195794ノート

反応式

HRID 1195794 の反応式
[S:1]([CH2:4][C:5]([C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)=O)[C:2]#[N:3].O.S(=O)(=O)(O)[OH:15]>C(O)(=O)C>[OH:15][C:2]1[S:1][CH:4]=[C:5]([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)[N:3]=1

参加物

5

反応物 3

HCID 962WaterHCID 1118Sulfuric AcidHCID 219693Phenacyl thiocyanate

生成物 1

HCID 178517449HCID 178517449、化合物

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

実験手順

Following the known process [Bull. Soc. Chem. France, 11, 2498 (1963)], 8.85 g (50 mmol) of α-thiocyanoacetophenone, 5 ml, of water and 1.3 ml of concentrated sulfuric acid were added to 40 ml of acetic acid and the resultant mixture was refluxed for 2 hours. The reaction mixture was then allowed to stand overnight at room temperature. Precipitated crystals were collected by filtration and then washed with water, whereby the title compound was obtained a colorless crystals.

後処理

  1. customPrecipitated crystals
  2. filtrationwere collected by filtration
  3. washwashed with water, whereby the title compound
  4. customwas obtained a colorless crystals

出典と根拠

ORDレコード
ord-25b346935638422f961fcb2edf117d7e
出典データセット
uspto-grants-1992_05
特許番号
US05112841

反応ノート

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