関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Triethoxychlorosilane | HCID 78398 | — |
| 反応物 | Sodium chlorodifluoroacetate | HCID 2734985 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | Chlorodifluoroacetic acid, triethoxysilyl ester | HCID 23523584 | — |
反応手順
15.246 g (0.10 mol) sodium chlorodifluoroacetate, is dissolved to 100 mL Et2O and cooled to −70° C. 19.7 mL (0.10 mol, 19.872 g) chlorotriethoxysilane in Et2O (50 mL) was added dropwise to reaction solution. The solution was stirred for over night allowing it to warm up to room temperature. NaCl is removed by filtration and solution evaporated to dryness to result clear colourless liquid, chlorodifluoroacetic acid, triethoxysilyl ester.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07098346B2 |
|---|
| 出典データセット | uspto-grants-2006_08 |
|---|
| ORD ID | ord-f1b5569857ad4bc69f007d641c3d1aae |
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| 出典メモ | uspto-grants-2006_08 |
|---|
