Chrysanthemic acid, cis-(-)- → Chrysanthemic Acid

HRID 1198857

反応式

HRID 1198857 の反応式
[CH3:1][C:2]([CH3:12])=[CH:3][C@H:4]1[C:6]([CH3:8])([CH3:7])[C@H:5]1[C:9]([OH:11])=[O:10].P(Br)(Br)Br>C1(C)C=CC=CC=1>[CH3:1][C:2]([CH3:12])=[CH:3][CH:4]1[C:6]([CH3:7])([CH3:8])[CH:5]1[C:9]([OH:11])=[O:10]

参加物

4

反応物 2

HCID 20755Chrysanthemic acid, cis-(-)-HCID 24614Phosphorus tribromide

生成物 1

HCID 2743Chrysanthemic Acid収率 90%

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

To a solution of cis chrysanthemic acid (1.0 g) in toluene (9 g) was added phosphorus tribromide (0.11 g) at room temperature under a nitrogen atmosphere. Irradiation with a xenon lamp (500 W, Pyrex glass filter) was made for 30 minutes under stirring. After the irradiation was over, similar after-treatment as in Example 1 was applied to obtain chrysanthemic acid (0.90 g). The isomer ratio of the product was: cis, 10.0%; and trans, 90.0%.

後処理

  1. customIrradiation with a xenon lamp
  2. filtration(500 W, Pyrex glass filter)
  3. customAfter the irradiation

出典と根拠

ORDレコード
ord-9944d14ec7c04c9781ccb8c4350716bb
出典データセット
uspto-grants-1990_02
特許番号
US04898655

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