Acetyl chloride → 4,4-Dinitrobutyl acetate

HRID 1199508ノート

反応式

HRID 1199508 の反応式
[N+:1]([CH:4]([N+:9]([O-:11])=[O:10])[CH2:5][CH2:6][CH2:7][OH:8])([O-:3])=[O:2].[C:12](Cl)(=[O:14])[CH3:13]>C(Cl)Cl>[C:12]([O:8][CH2:7][CH2:6][CH2:5][CH:4]([N+:9]([O-:11])=[O:10])[N+:1]([O-:3])=[O:2])(=[O:14])[CH3:13]

参加物

4

反応物 2

HCID 6367Acetyl chlorideHCID 144017664,4-Dinitrobutan-1-ol

生成物 1

HCID 144017674,4-Dinitrobutyl acetate

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

This ester was synthesized by treating a solution of 4,4-dinitro-1-butanol (39.2 g, 0.24 mols) in CH2Cl2 (100 ml) with acetyl chloride (22 ml, 24 g, 0.31 mol). After 90 minutes at room temperature, the reaction was quenched with ice water. Separation, drying (MgSO4), and concentration of the organic phase gave the product (42.7 g, 87%) as a light yellow oil; nD =1.4574 (24C). The infrared spectrum of the product had peaks at 2960, 1745, 1575, 1245, and 1060 cm-1. Elemental analyses-Calculated for C6H10N2O6 : C, 34.95; H, 4.85; N, 13.59; Found: C, 35.17; H, 4.83; N, 12.95.

後処理

  1. customthe reaction was quenched with ice water
  2. customSeparation
  3. dry with materialdrying (MgSO4), and concentration of the organic phase

出典と根拠

ORDレコード
ord-cf1ae0a1194d4a8491da65d770a89a86
出典データセット
uspto-grants-1990_02
特許番号
US04900851

反応ノート

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